Issue 1, 1995

An orthometallated cyclopentadienyl phosphine bridge in a new type of heterobimetallic complex: [(η5-C5H5)(η5-C5H4)Mo{o-C6H4P(Ph)Cr(CO)5}]X (X = Cl, I)

Abstract

An unexpected product is obtained during the reaction between (η5-C5H5)2MoCl2 and Li[Cr(CO)5(PPh2)] resulting in the formation of a dinuclear complex with the novel [(η5-C5H4) PPh(Cr{CO)5}C6H4] ligand; the crystal structure of one derivative is reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 45-46

An orthometallated cyclopentadienyl phosphine bridge in a new type of heterobimetallic complex: [(η5-C5H5)(η5-C5H4)Mo{o-C6H4P(Ph)Cr(CO)5}]X (X = Cl, I)

S. Rigny, J. Leblanc, C. Moïse and B. Nuber, J. Chem. Soc., Chem. Commun., 1995, 45 DOI: 10.1039/C39950000045

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