Reactions of acetonide derivatives of glucose, allose, galactose and fructose with MeMgI in benzene under reflux afford the corresponding monosaccharide derivatives having only one free hydroxy group in moderate to good yield.
Y. Chen, T. Luh, G. Lee and S. Peng, J. Chem. Soc., Chem. Commun., 1994, 2369 DOI: 10.1039/C39940002369
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