Issue 15, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Design of complex–ligand systems based on thiouracil. A novel cyclic tetramer of cobalt(III) with 1-(2-thiouracil-4-methylene)-3,6-diazahexane

Takashi Kajiwara  and  Tasuku Ito  

Abstract

A Schiff base derived from 2-thiouracil-4-aldehyde and dien reacts with CoII(CF3SO3)2 to afford a novel cyclic tetramer of cobalt(III) by self-assembly; the complex has a columnar cavity at its centre with an effective diameter of ca. 1.8 Å.

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Article information

DOI
https://doi.org/10.1039/C39940001773
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1773-1774

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Design of complex–ligand systems based on thiouracil. A novel cyclic tetramer of cobalt(III) with 1-(2-thiouracil-4-methylene)-3,6-diazahexane

T. Kajiwara and T. Ito, J. Chem. Soc., Chem. Commun., 1994, 1773 DOI: 10.1039/C39940001773

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