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Issue 7, 1994
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Reaction of diphenylketene with some cyclohexa-3,5-diene-1,2-cis-diol derivatives: conversion of chlorobenzene into optically active 2-oxabicyclo[2.2.2]octen-3-one

Abstract

The dienes 11–15 react with diphenylketene to give mixtures of the corresponding [2 + 2]-adducts 16–20 and [4 + 2]-adducts 21–25: the isomers 19/24 were converted into the optically active lactone 26 in two steps.

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Article type: Paper
DOI: 10.1039/C39940000803
Citation: J. Chem. Soc., Chem. Commun., 1994, 803-804
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    Reaction of diphenylketene with some cyclohexa-3,5-diene-1,2-cis-diol derivatives: conversion of chlorobenzene into optically active 2-oxabicyclo[2.2.2]octen-3-one

    C. A. Pittol, S. M. Roberts, P. W. Sutton and J. O. Williams, J. Chem. Soc., Chem. Commun., 1994, 803
    DOI: 10.1039/C39940000803

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