The alkali–metal fullerides C60M6 and C70M6(M = Cs, K, Na) exhibit remarkable catalytic activities in H2–D2 exchange at 173–273 K and ethene hydrogenation at 273–373 K which resemble that of noble metals such as Pt and Pd; uncombined fullerenes and alkali metals are inactive.
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Journal of the Chemical Society, Chemical Communications
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