Issue 3, 1994

Nucleophilic additions to a diphosphirenium salt: ring opening and ring expansion reactions

Abstract

P-Bis(diisopropylamino)-C-diisopropylamino diphosphirenium tetrafluoroborate 1 reacts with lithium diisopropylamide and tert-butyl isocyanide affording phosphaalkene 3 and the original four-membered heterocycle 5;5 is characterized by X-ray diffraction and its chemical reactivity.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 337-338

Nucleophilic additions to a diphosphirenium salt: ring opening and ring expansion reactions

M. Soleilhavoup, A. Baceiredo, F. Dahan and G. Bertrand, J. Chem. Soc., Chem. Commun., 1994, 337 DOI: 10.1039/C39940000337

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