SCHEDULED MAINTENANCE
The exploitation of size-complementarity between the macrocyclic component and the stoppers of the dumbbell component of a [2]rotaxane, together with stabilising noncovalent bonding interactions that create a thermodynamic trap, have permitted the development of an alternative method, which can be termed slippage, for the syntheses of [2]rotaxanes in good yields.
P. R. Ashton, M. Bělohradský, D. Philp and J. F. Stoddart, J. Chem. Soc., Chem. Commun., 1993, 1269 DOI: 10.1039/C39930001269
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