SCHEDULED MAINTENANCE
Tricyclic ligands incorporating bis(thiourea) subunits may be prepared from the corresponding monocyclic [18]- and [24]-ring N4O2 and N4O4 polyaza-compounds and adopt a trans-conformation in the free ligand; an unusual trisilver(I) complex is formed with the N4O2-derived ligand with bridging nitrate groups in which the thiourea groups are cis-oriented.
M. Rosser, D. Parker, G. Ferguson, J. F. Gallagher, J. A. K. Howard and D. S. Yufit, J. Chem. Soc., Chem. Commun., 1993, 1267 DOI: 10.1039/C39930001267
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