Issue 5, 1993

The oxidation of tantalum with ammonium chloride as an example of a novel route to early transitional metal–nitrogen cluster compounds. Synthesis and crystal structure of (NH4)6[Ta5(NH)4Cl17]

Abstract

The oxidation of tantalum metal with ammonium chloride leads to dark-green single crystals of (NH4)6[Ta5(NH)4Cl17], a new imido-bridged tantalum-cluster compound with the [Ta5(NH)4Cl17]6– anion.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 460-461

The oxidation of tantalum with ammonium chloride as an example of a novel route to early transitional metal–nitrogen cluster compounds. Synthesis and crystal structure of (NH4)6[Ta5(NH)4Cl17]

M. Simon and G. Meyer, J. Chem. Soc., Chem. Commun., 1993, 460 DOI: 10.1039/C39930000460

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