Issue 24, 1992

Addition of alkynes to (vinylketene)tricarbonyliron(0) complexes

Abstract

Alkynes add to (vinylketene)tricarbonyliron(0) complexes to generate stable adducts; addition of unsymmetrical alkynes is highly regioselective and the regiochemistries of the adducts produced in these reactions were determined by X-ray crystal structure analyses of the major isomer derived from but-3-yn-2-one and (3-tert-butyl-5-phenyl-1-oxapenta-1,2,4-triene)tricarbonyliron(0), and of the structurally modified product derived from diethylpropynylamine and (3-isopropyl-5-phenyl-1-oxapenta-1,2-4-triene)tricarbonyliron(0).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1788-1791

Addition of alkynes to (vinylketene)tricarbonyliron(0) complexes

K. G. Morris, S. P. Saberi, A. M. Z. Slawin, S. E. Thomas and D. J. Williams, J. Chem. Soc., Chem. Commun., 1992, 1788 DOI: 10.1039/C39920001788

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