Issue 17, 1992

The surprisingly facile dehydrohalogenation of a hydrazonoyl chloride into a stable phosphorus-substituted nitrilimine

Abstract

Tetrachloro-o-benzoquinone reacts with bis(diisopropylamino)thioxophosphoranenitrile N-[(phenyl)(2,4,6-trifluoromethylphenyl)phosphanyl]imide 1b affording the corresponding σ5λ5-phosphorus-substituted nitrilimine 2b; addition of HCl to 2b leads to hydrazonoyl chloride 4b which gives back nitrilimine 2b by simple filtration on silica gel.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1274-1276

The surprisingly facile dehydrohalogenation of a hydrazonoyl chloride into a stable phosphorus-substituted nitrilimine

F. Castan, A. Baceiredo, F. Dahan, N. Auner and G. Bertrand, J. Chem. Soc., Chem. Commun., 1992, 1274 DOI: 10.1039/C39920001274

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