The syntheses, acid-catalysed rearrangements and demetallation chemistry of CpW(CO)3(η1-[graphic omitted]H2)(R = CHCH2, C![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CPh; R1= alkyl, phenyl; Cp = C5H5) are reported, and their synthetic-utility in organic reactions is demonstrated.
M. Cheng, G. Yang, J. Chow, G. Lee, S. Peng and R. Liu, J. Chem. Soc., Chem. Commun., 1992, 934 DOI: 10.1039/C39920000934
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