Issue 11, 1992

Tetrathiorhenate(VI), ReS42–. Spectroelectrochemical characterization (UV–VIS–IR) of a small new d1 system and of its tetrakis(2,2′-bipyridine)diruthenium(II) complex (EPR)

Abstract

ReS42– is the first d1 tetrathiometallate persistent enough to be studied with respect to change transfer, ligand field and IR vibrational spectra via spectroelectrochemistry; an EPR spectrum could only be detected of its trinuclear derivative [(bpy)2Ru(µ-ReS4)Ru(bpy)2]2+(bpy = 2,2′-bipyridine) at 4 K.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 834-835

Tetrathiorhenate(VI), ReS42–. Spectroelectrochemical characterization (UV–VIS–IR) of a small new d1 system and of its tetrakis(2,2′-bipyridine)diruthenium(II) complex (EPR)

R. Schäfer, W. Kaim, M. Moscherosch and M. Krejčik, J. Chem. Soc., Chem. Commun., 1992, 834 DOI: 10.1039/C39920000834

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