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Issue 3, 1992
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Isolation, structure and MO calculational investigations of a highly stable, hydrogen-bonded primary amine–phosphine oxide adduct, 2-aminobenzothiazole–HMPA, C6H4SC([double bond, length half m-dash]N)NH2O[double bond, length half m-dash]P(NMe2)3; a possible model to explain the carcinogenicity of HMPA (HMPA = hexamethylphosphoramide)

Abstract

Colourless needles of the 1 : 1 primary amine–phosphine oxide adduct [graphic omitted] are obtained in high yield simply by chilling a toluene solution of the two components; the solid-state structure of the highly stable adduct (which can be prepared in water, and which sublimes easily) consists essentially of dimers held by (amine) N–H ⋯ O and (amine)N–H ⋯(heterocyclic) N hydrogen bonds.

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Article type: Paper
DOI: 10.1039/C39920000262
Citation: J. Chem. Soc., Chem. Commun., 1992,0, 262-264
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    Isolation, structure and MO calculational investigations of a highly stable, hydrogen-bonded primary amine–phosphine oxide adduct, 2-aminobenzothiazole–HMPA, C6H4SC([double bond, length half m-dash]N)NH2O[double bond, length half m-dash]P(NMe2)3; a possible model to explain the carcinogenicity of HMPA (HMPA = hexamethylphosphoramide)

    D. R. Armstrong, S. Bennett, M. G. Davidson, R. Snaith, D. Stalke and D. S. Wright, J. Chem. Soc., Chem. Commun., 1992, 0, 262
    DOI: 10.1039/C39920000262

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