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Issue 20, 1991
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Oxidatively induced radical chemistry of dicarbonyl η5-cyclopentadienyl iron derivatives of carboxylic acids (Fp–acyl complexes)

Abstract

The 17-electron cationic [Fp–acyl] intermediates generated by cerium ammonium nitrate (CAN) oxidation of Fp–acyl complexes in dry acetonitrile undergo a fast homolytic dissociation leading to alkyl radical species whose subsequent fate is dependent on the structural features and reaction conditions.

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Article type: Paper
DOI: 10.1039/C39910001458
Citation: J. Chem. Soc., Chem. Commun., 1991,0, 1458-1460
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    Oxidatively induced radical chemistry of dicarbonyl η5-cyclopentadienyl iron derivatives of carboxylic acids (Fp–acyl complexes)

    C. Amiens, G. Balavoine and F. Guibé, J. Chem. Soc., Chem. Commun., 1991, 0, 1458
    DOI: 10.1039/C39910001458

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