Framework ordering in solid cadmium cyanides from cadmium-113 NMR spectroscopy
Abstract
On the basis of solid state 113Cd NMR spectra an ordering scheme is proposed for the cyanide units in the framework host lattice of Cd(CN)2·2/3H2O·ButOH which differs from that derived from X-ray diffraction data and which dictates a different choice of space group.