Issue 24, 1990

Cleavage of an aryl carbon–sulphur bond in hydride–thiolate complexes of molybdenum(IV); X-ray crystal structure of [{Mo(SC6H2Pri3-2,4,6)(OMe)(PMePh2)}2(µ-S)2]

Abstract

The complexes [MoH(SC6H2R3-2,4,6)3(PR′Ph2)]1(R = Me or Pri; R′= Me or Et) in THF–MeOH decompose via cleavage of an aryl carbon–sulphur bond to give C6H3R3-2,4,6 and complexes [{Mo(SC6H2R3-2,4,6)(OMe)(PR′Ph2)}2(µ-S)2], 3, one of which (R = Pri, R′= Me) has been characterized by single crystal X-ray diffraction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1757-1759

Cleavage of an aryl carbon–sulphur bond in hydride–thiolate complexes of molybdenum(IV); X-ray crystal structure of [{Mo(SC6H2Pri3-2,4,6)(OMe)(PMePh2)}2(µ-S)2]

T. E. Burrow, A. Hills, D. L. Hughes, J. D. Lane, N. J. Lazarowych, M. J. Maguire, R. H. Morris and R. L. Richards, J. Chem. Soc., Chem. Commun., 1990, 1757 DOI: 10.1039/C39900001757

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