Novel sulphide frameworks: synthesis and X-ray structural characterization of Cs6Sb10S18·1.2H2O
Abstract
New antimony sulphides have been synthesized and the crystal structure of one of these, Cs6Sb10S18·1.2H2O, has been determined to be two dimensional in nature, accommodating Cs+ ions and the Sb3+ Ione pairs in cavities within an open framework.