Issue 16, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Biosynthesis of vitamin B12: formation of pyrrocorphins by peripheral C-methylation of precorrin-3 octamethyl ester

Colin L. Gibson,   Francis Blanche  and  Alan R. Battersby  

Abstract

The ester of precorrin-3 (4) is converted by metallation tautomerisation followed by C-methylation and tautomerisation-demetallation into a family of isomers from which are isolated trans-, and cis-Cpyrrocorphins for biosynthetic studies on vitamin B12.

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Article information

DOI
https://doi.org/10.1039/C39900001123
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1123-1125

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Biosynthesis of vitamin B12: formation of pyrrocorphins by peripheral C-methylation of precorrin-3 octamethyl ester

C. L. Gibson, F. Blanche and A. R. Battersby, J. Chem. Soc., Chem. Commun., 1990, 1123 DOI: 10.1039/C39900001123

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