Issue 23, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

Stoicheiometric dimerisation of methyl acrylate mediated by Pd(acac)2·HBF4 systems and its relevance to the mechanism of catalytic dimerisation of acrylates (Hacac = MeCOCH2COMe)

Isabelle Guibert,   Denis Neibecker  and  Igor Tkatchenko  

Abstract

Protonation of Pd(acac)2(Hacac = MeCOCH2COMe) by HBF4·OEt2 leads to ionic [Pd(acac)S2][BF4] complexes, isolated for S = MeCN, which react with methyl acrylate to give selectively linear dimers via a palladium(IV) metallocycle.

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Article information

DOI
https://doi.org/10.1039/C39890001850
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1850-1852

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Stoicheiometric dimerisation of methyl acrylate mediated by Pd(acac)2·HBF4 systems and its relevance to the mechanism of catalytic dimerisation of acrylates (Hacac = MeCOCH2COMe)

I. Guibert, D. Neibecker and I. Tkatchenko, J. Chem. Soc., Chem. Commun., 1989, 1850 DOI: 10.1039/C39890001850

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