Issue 14, 1989

A regio-, (E)-stereo-, and chemo-selective synthesis of unsymmetrical divinylmethanols starting from L- and D-tartrates via organocyanocopper Lewis acid mediated 1,3-chirality transfer

Abstract

A regio-, (E)-stereo-, and chemo-selective synthesis of synthetically useful unsymmetrical divinylmethanol derivatives, compounds that are not easily accessible by other means, via an organocyanocopper·BF3 mediated 1,3-chirality transfer in mixed solvents involving tetrahydrofuran at –78 °C is reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 967-969

A regio-, (E)-stereo-, and chemo-selective synthesis of unsymmetrical divinylmethanols starting from L- and D-tartrates via organocyanocopper Lewis acid mediated 1,3-chirality transfer

T. Ibuka, M. Tanaka and Y. Yamamoto, J. Chem. Soc., Chem. Commun., 1989, 967 DOI: 10.1039/C39890000967

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