SCHEDULED MAINTENANCE
The photolytic reaction of (Cp)Rh(PMe3)(C2H4), (1, Cp=η5-C5H5) with benzene yields (Cp)Rh(PMe3)(Ph)H via a transient η2-C6F6 complex detected by laser flash photolysis; the corresponding reaction of (1) with C6F6 yields (C)Rh(PMe3)(η2-C6F6) which contains an almost planar C6F4 unit with the remaining fluorines bent out of the plane by 43 °.
S. T. Belt, S. B. Duckett, M. Helliwell and R. N. Perutz, J. Chem. Soc., Chem. Commun., 1989, 928 DOI: 10.1039/C39890000928
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