The detection of connectivities of rare spin-½ nuclei in the solid state using natural abundance samples: 13C and 29Si INADEQUATE and COSY type experiments
Abstract
The cross polarization (c.p.)–magic angle spinning (m.a.s.)–INADEQUATE and c.p.–m.a.s.–COSY techniques for detection of connectivities of rare spin-½ nuclei in the solid state are introduced and illustrated using the scalar 1J(13C,13C) and 2J(29Si,29Si) soupling of natural abundance samples.