Issue 12, 1987

Crown thioether chemistry: synthesis and characterisation of bis(1,4,7-trithiacyclononane)silver(I) trifluoromethanesulphonate, an octahedral homoleptic thioether complex of AgI showing unusually facile oxidation

Abstract

1,4,7-Trithiacyclononane (9S3) reacts with soluble silver(I) salts to form [Ag(9S3)2]+, a monomeric complex that has a distorted octahedral structure and is readily oxidised to the silver(II) complex.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 950-951

Crown thioether chemistry: synthesis and characterisation of bis(1,4,7-trithiacyclononane)silver(I) trifluoromethanesulphonate, an octahedral homoleptic thioether complex of AgI showing unusually facile oxidation

J. Clarkson, R. Yagbasan, P. J. Blower, S. C. Rawle and S. R. Cooper, J. Chem. Soc., Chem. Commun., 1987, 950 DOI: 10.1039/C39870000950

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