Issue 3, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of high-nuclearity carbonyl–phosphine clusters of palladium under mild conditions and X-ray crystal structure of Pd38(µ3-CO)4(µ2-CO)24(PEt3)12

Eugenii G. Mednikov,   Nikolai K. Eremenko,   Yuri L. Slovokhotov  and  Yuri T. Struchkov  

Abstract

The large Pd38(CO)28(PEt3)12 carbonyl–phosphine cluster, obtained by a general phosphine abstracting route by the action of Pd(OAc)2 on the ten-vertex Pd10(CO)12(PEt3)6 cluster, is shown by an X-ray study to contain a four-layer fragment of a distorted cubic close packing with an interstitial Pd4 tetrahedron.

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Article information

DOI
https://doi.org/10.1039/C39870000218
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 218-219

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Synthesis of high-nuclearity carbonyl–phosphine clusters of palladium under mild conditions and X-ray crystal structure of Pd38(µ3-CO)4(µ2-CO)24(PEt3)12

E. G. Mednikov, N. K. Eremenko, Y. L. Slovokhotov and Y. T. Struchkov, J. Chem. Soc., Chem. Commun., 1987, 218 DOI: 10.1039/C39870000218

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