Issue 1, 1987

Allylic activation by copper(I): reactivity comparable with catalysis by palladium

Abstract

Allylic chlorides and acetates accelerate the reaction between copper(II) perchlorate and copper metal powder to form copper(I) perchlorate which in turn is an extremely good catalyst for the activation of these substrates towards nucleophilic substitution.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 36-37

Allylic activation by copper(I): reactivity comparable with catalysis by palladium

J. B. Baruah and A. G. Samuelson, J. Chem. Soc., Chem. Commun., 1987, 36 DOI: 10.1039/C39870000036

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