Issue 23, 1986

A series of µ-disulphido–dimolybdenum(IV) complexes: X-ray structure of the novel (µ-tetrahydrothiophene) complex [(C4H8S)Cl3Mo(µ-S2)(µ-C4H8S)MoCl3(C4H8S)]

Abstract

The complexes [Mo2(µ-S2)Cl6L3](L = C4H8O or C4H8S); [Mo2(µ-S2)Cl6L2](L = C4H8O, MeCN, 4-MeOC6H4CN, 2-MeC5H4N, or 2,6-Me2C5H3N) and [PPh4]2[Mo2S2Cl8] have been prepared; the X-ray structure of [(C4H8S)Cl3Mo(µ-S2)(µ-C4H8S)MoCl3(C4H8S)] shows and unusual bridging C4H8S ligand.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1731-1732

A series of µ-disulphido–dimolybdenum(IV) complexes: X-ray structure of the novel (µ-tetrahydrothiophene) complex [(C4H8S)Cl3Mo(µ-S2)(µ-C4H8S)MoCl3(C4H8S)]

D. L. Hughes, R. L. Richards and C. Shortman, J. Chem. Soc., Chem. Commun., 1986, 1731 DOI: 10.1039/C39860001731

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