A series of µ-disulphido–dimolybdenum(IV) complexes: X-ray structure of the novel (µ-tetrahydrothiophene) complex [(C4H8S)Cl3Mo(µ-S2)(µ-C4H8S)MoCl3(C4H8S)]
Abstract
The complexes [Mo2(µ-S2)Cl6L3](L = C4H8O or C4H8S); [Mo2(µ-S2)Cl6L2](L = C4H8O, MeCN, 4-MeOC6H4CN, 2-MeC5H4N, or 2,6-Me2C5H3N) and [PPh4]2[Mo2S2Cl8] have been prepared; the X-ray structure of [(C4H8S)Cl3Mo(µ-S2)(µ-C4H8S)MoCl3(C4H8S)] shows and unusual bridging C4H8S ligand.