Use of the skeletal rearrangement and the hydrogenolysis of n-hexane as probe reactions, and interaction with titania as a means of modifying catalytic properties, has provided evidence that the active centre in Pt catalysts consists of only a single metal atom in a unique environment.
J. B. F. Anderson, R. Burch and J. A. Cairns, J. Chem. Soc., Chem. Commun., 1986, 1647 DOI: 10.1039/C39860001647
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