Owing to its topography, the catenand (3) forms highly inert copper(I) or proton catenates; the dissociation rate law indicates that, in contrast with complexes of (2), no important geometrical change takes place during decomplexation.
A. Albrecht-Gary, C. Dietrich-Buchecker, Z. Saad, J. Sauvage and J. Weiss, J. Chem. Soc., Chem. Commun., 1986, 1325 DOI: 10.1039/C39860001325
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