The anion [Rh10(CO)21]2–, obtained by reaction of [Rh9(CO)19]3– with the [Rh(CO)2(NCMe)2]+ cation, contains a novel decanuclear metallic skeleton which is a fragment of hexagonal close-packed lattice formed by three superimposed layers (3/4/3 metals), with two octahedral and two tetrahedral condensed units as confirmed by X-ray crystallography.
S. Martinengo, G. Ciani and A. Sironi, J. Chem. Soc., Chem. Commun., 1986, 1282 DOI: 10.1039/C39860001282
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