Issue 22, 1985

Nitrosyl ligand related metal polyhedron isomerism; syntheses of [N(PPh3)2][Ru5C(CO)13(NO)(AuPR3)](R = Et, Ph) and the X-ray structure analysis of [Ru5C(CO)13(NO)(µ3-AuPEt3)] and [Ru5C(CO)13(NO)(µ2-AuPEt3)] in one crystal

Abstract

The new nitrosyl monoanion [Ru5C(CO)13(NO)](1) has been prepared by reaction of [Ru5C(CO)15] with [NO2], and it reacts with [AuPR3]+(R = Et, Ph) to give [Ru5C(CO)13(NO)(AuPR3)]; X-ray structure analysis of one of these compounds [Ru5C(CO)13(NO)(AuPEt3)](2) shows that it exists as isomers (2A) and (2B) which differ in the bonding mode of the Au ligand and in its site relative to the nitrosyl ligand.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1617-1618

Nitrosyl ligand related metal polyhedron isomerism; syntheses of [N(PPh3)2][Ru5C(CO)13(NO)(AuPR3)](R = Et, Ph) and the X-ray structure analysis of [Ru5C(CO)13(NO)(µ3-AuPEt3)] and [Ru5C(CO)13(NO)(µ2-AuPEt3)] in one crystal

K. Henrick, B. F. G. Johnson, J. Lewis, J. Mace, M. McPartin and J. Morris, J. Chem. Soc., Chem. Commun., 1985, 1617 DOI: 10.1039/C39850001617

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