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The isotope shift caused by 17O or 18O on the frequency of the symmetric and antisymmetric ![[double bond splayed left]](https://www.rsc.org/images/entities/char_e009.gif)
SO2 stretching modes of 2,2-dioxo-1,3,2-dioxathianes (six-membered cyclic sulphates) is strongly dependent on whether the heavy oxygen isotope is located in an axial or equatorial site.
G. Lowe and M. J. Parratt, J. Chem. Soc., Chem. Commun., 1985, 1073 DOI: 10.1039/C39850001073
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