Issue 22, 1984

Perchlorovinylcarbene: a bulky electrophile

Abstract

The carbene selectivity index mcxy for perchlorovinylcarbene [Cl2C[double bond, length half m-dash]CClC(Cl):] was determined by competition experiments with different substituted olefins as ∼0.38, whereas the value calculated from Moss's equation is 0.34 ± 0.1; this proves at least qualitatively that perchlorovinylcarbene is an electrophilic carbene.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1528-1529

Perchlorovinylcarbene: a bulky electrophile

R. Kostikov and A. de Meijere, J. Chem. Soc., Chem. Commun., 1984, 1528 DOI: 10.1039/C39840001528

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