Issue 15, 1984

Acceleration of the reductive elimination step in Pd-catalysed allylic alkylation by allylic substrates

Abstract

Allylic electrophiles used in Pd-catalysed allysic alkylation greatly accelerate reductive elimination of η3-allyl(organo)palladium(II) complexes, via a PdIV intermediate, to give the coupling products and η3-allylpalladium(II) salts.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 968-969

Acceleration of the reductive elimination step in Pd-catalysed allylic alkylation by allylic substrates

H. Kurosawa, M. Emoto and A. Urabe, J. Chem. Soc., Chem. Commun., 1984, 968 DOI: 10.1039/C39840000968

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements