Reduction of Cx2NPCl2(Cx = cyclohexyl) with LiAlH4 gives Cx2NPH2 as an isolable air-sensitive liquid which can be converted into the relatively stable metal carbonyl complexes Cx2NPH2M(CO)5(M = Cr and W) and Cx2NPH2Fe(CO)4; the 2,2,6,6-tetramehtylpiperidiono derivative [graphic omitted]PH2 is also isolable and the diisopropylamino derivative Pri2NPH2 has been detected in solution by 31P n.m.r. spectroscopy.
R. B. King and N. D. Sadanani, J. Chem. Soc., Chem. Commun., 1984, 955 DOI: 10.1039/C39840000955
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