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Synthesis of (–)-ajmalicine from (–)-tryptophan
Abstract
(–)-Tryptophan has been converted into(–)-ajmalicine in 15 steps; the key step is an intramolecular Michael reaction in which the C(15)–C(20) bond is formed with full stereocontrol.
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Article information
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J. Chem. Soc., Chem. Commun., 1984, 715-716
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Synthesis of (–)-ajmalicine from (–)-tryptophan
G. Massiot and T. Mulamba, J. Chem. Soc., Chem. Commun., 1984, 715 DOI: 10.1039/C39840000715
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