The L-proline residue in oligopeptides has been shown to act as a ‘break-point’ in their co-ordination to copper(II) ions leading to the formation of large chelate rings with the peptide locked in the β-conformation.
M. Bataille, G. Formicka-Kozlowska, H. Kozlowski, L. D. Pettit and I. Steel, J. Chem. Soc., Chem. Commun., 1984, 231 DOI: 10.1039/C39840000231
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