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The decomposition of o-azidodiphenylmethanes by flash vacuum pyrolysis (f.v.p.)(350–700 °C) gives acridan and acridine in contrast with the production of 10H-azepinoindole at lower temperatures in solution; similar f.v.p. treatment of 10H-azepinoindole gives some of the tautomeric 6H-azepinoindole.
M. G. Hicks and G. Jones, J. Chem. Soc., Chem. Commun., 1983, 1277 DOI: 10.1039/C39830001277
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