I.r. spectroscopic evidence, including 13CO labelling and energy-factored force-field fitting, is presented to show that photolysis of [(η5-C5H5)Cr(CO)3CH3] in gas matrices at 12 K leads to a methylene hydride species, [(η5-C5H5)Cr(CO)2(CH2)H], following CO dissociation and α-H elimination reactions and that this process is reversible.
K. A. Mohmoud, A. J. Rest and H. G. Alt, J. Chem. Soc., Chem. Commun., 1983, 1011 DOI: 10.1039/C39830001011
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