Issue 16, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Activation of a carbonyl group in the pentanuclear carbido clusters Os5C(CO)15 and I2Os5C(CO)15 by alcohols: X-ray analysis of HOs5C(CO)14(CO2Et) and IOs5C(CO)14(CO2Me)

Dario Braga,   Brian F. G. Johnson,   Jack Lewis,   Mary McPartlin,   William J. H. Nelson,   J. Nichola Nicholls  and  Maria D. Vargas  

Abstract

The clusters Os5C(CO)15 and I2Os5C(CO)15 react with alcohols under mild conditions to give derivatives of the type HOs5C(CO)14(CO2R) and IOs5C(CO14)(CO2R), reapectively; X-ray analysis has confirmed that in both cases the alkoxy-group has attacked a carbonyl ligand in the parent compound to form an η2-µ2-CO2R Group.

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Article information

DOI
https://doi.org/10.1039/C39820000966
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 966-967

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Activation of a carbonyl group in the pentanuclear carbido clusters Os5C(CO)15 and I2Os5C(CO)15 by alcohols: X-ray analysis of HOs5C(CO)14(CO2Et) and IOs5C(CO)14(CO2Me)

D. Braga, B. F. G. Johnson, J. Lewis, M. McPartlin, W. J. H. Nelson, J. N. Nicholls and M. D. Vargas, J. Chem. Soc., Chem. Commun., 1982, 966 DOI: 10.1039/C39820000966

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