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Issue 9, 1981
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Complexing properties of a bisdianhydro-D-mannitolo-30-crown-10 derivative in the solution and solid states; X-ray crystal structure

Abstract

X-Ray crystallography has revealed that the chiral 30-crown-10 derivative DD-(2) adopts a basket like conformation when it forms a 1 : 1 :1 complex with (S)-[PhCHMeNH3]+ CIO4 and H2O in the solid state; 1H n.m.r. spectroscopy suggests that 1:1:1 complexes of this type between (i)DD-(2), R1NH3+ cations, and H2O, and (ii)DD-(2), R1NH3+ cations, and R2NH2 are also stable in solution.

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Article type: Paper
DOI: 10.1039/C39810000432
Citation: J. Chem. Soc., Chem. Commun., 1981,0, 432-434
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    Complexing properties of a bisdianhydro-D-mannitolo-30-crown-10 derivative in the solution and solid states; X-ray crystal structure

    J. C. Metcalfe, J. F. Stoddart, G. Jones, T. H. Crawshaw, E. Gavuzzo and D. J. Williams, J. Chem. Soc., Chem. Commun., 1981, 0, 432
    DOI: 10.1039/C39810000432

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