Jump to main content
Jump to site search

Issue 9, 1981
Previous Article Next Article

Some transition metal complexes of pentakis(methoxycarbonyl)cyclopentadiene: water-soluble metallocenes, and the X-ray crystal structure of Ru(η-C5H5)[η-C5(CO2Me)5]

Abstract

Some metal derivatives of the [C5(CO2Me)5] anion (cpp) are described, of which transition metal complexes M(cpp)2 are fully ionised in aqueous solution and the mixed complex Ru(η-C5H5)[η-C5(CO2Me)5] contains a symmetrically bonded cpp ring; covalent Group IB metal complexes M1(cpp)(PPh3) react further with PPh3 to give ionic [M(PPh3)2](cpp).

Back to tab navigation
Please wait while Download options loads

Article type: Paper
DOI: 10.1039/C39810000428
Citation: J. Chem. Soc., Chem. Commun., 1981, 428-430
  •   Request permissions

    Some transition metal complexes of pentakis(methoxycarbonyl)cyclopentadiene: water-soluble metallocenes, and the X-ray crystal structure of Ru(η-C5H5)[η-C5(CO2Me)5]

    M. I. Bruce, B. W. Skelton, R. C. Wallis, J. K. Walton, A. H. White and M. L. Williams, J. Chem. Soc., Chem. Commun., 1981, 428
    DOI: 10.1039/C39810000428

Search articles by author