Detailed energy balance studies of the single-collision chemiluminescent reactions of metastable strontium atoms with thionyl fluoride and sulphuryl fluoride yield the bond dissociation energies: D0⊖(FSO–F) 362 ± 19, D0⊖(SO–F) 337 ± 106, D0⊖(FSO2–F) 379 ± 18, and D0⊖(SO2–F) 229 ± 20 kJ mol–1.
T. Kiang and R. N. Zare, J. Chem. Soc., Chem. Commun., 1980, 1228 DOI: 10.1039/C39800001228
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