An ion cyclotron resonance (i.c.r.) study has shown that gas phase hardness of dialkyl ketones and alkyl alcohols increases with increasing substitution, but decreases with decreasing ring size.
I. A. Blair, J. H. Bowie and V. C. Trenerry, J. Chem. Soc., Chem. Commun., 1979, 230 DOI: 10.1039/C39790000230
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