Evidence has been obtained using e.s.r. spectroscopy that arenesulphinyl radicals (ArSO·) are produced during the thermal and photolytic homolysis of both diaryl sulphoxides and S-aryl arenethiosulphonates, in the latter case via the initial production of the corresponding sulphonyl and thiyl radicals, ArSO2· and ArS·, respectively.
B. C. Gilbert, B. Gill and M. D. Sexton, J. Chem. Soc., Chem. Commun., 1978, 78 DOI: 10.1039/C39780000078
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