Issue 23, 1977
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray crystal structure of hexakis(trimethylphosphine)tris-µ-methylene-diruthenium(III)

Richard A. Andersen,   Richard A. Jones,   Geoffrey Wilkinson,   Michael B. Hursthouse  and  K. M. Abdul Malik  

Abstract

The reaction between the dinuclear ruthenium-(II.III)-bridged acetate Ru2(O2CMe)4Cl and MgMe2 in presence of PMe3 produces the complex Ru2(CH2)3(PMe3)6(A) in low yield; higher yields are obtained if the trimeric µ3-oxo-centred acetate [Ru3O(O2CMe)6(H2O)3]·(O2CMe) is used and the structure of (A) has been determined by X-ray crystallography and contains three methylene bridges.

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Article information

DOI
https://doi.org/10.1039/C39770000865
Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 865-866

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Synthesis and X-ray crystal structure of hexakis(trimethylphosphine)tris-µ-methylene-diruthenium(III)

R. A. Andersen, R. A. Jones, G. Wilkinson, M. B. Hursthouse and K. M. A. Malik, J. Chem. Soc., Chem. Commun., 1977, 865 DOI: 10.1039/C39770000865

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