Issue 15, 1977
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel bimetallic products from octacarbonyldicobalt and methyl-aminobis(difluorophosphine); X-ray crystal structures of [{MeN(PF2)2}3Co2(PF2NHMe)2] and [{Men(PF2)2}3Co2(CO)2]

M. Gary Newton,   R. Bruce King,   Main Chang,   Nantelle S. Pantaleo  and  Jose Gimeno  

Abstract

Reactions of [Co2(CO)8] with an excess of MeN(PF2)2 under various conditions give compounds of the general type [{MeN(PF2)2}3Co2L2](L = MeNHPF2 or CO) shown by single crystal X-ray diffraction to contain a cobalt-cobalt bond bridged by three MeN-(PF2)2 ligands.

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Article information

DOI
https://doi.org/10.1039/C39770000531
Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 531-532

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Novel bimetallic products from octacarbonyldicobalt and methyl-aminobis(difluorophosphine); X-ray crystal structures of [{MeN(PF2)2}3Co2(PF2NHMe)2] and [{Men(PF2)2}3Co2(CO)2]

M. G. Newton, R. B. King, M. Chang, N. S. Pantaleo and J. Gimeno, J. Chem. Soc., Chem. Commun., 1977, 531 DOI: 10.1039/C39770000531

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