Geminal bromo-nitro compounds are reduced by N-benzyl-1,4-dihydronicotinamide (1; R = PhCH2) to the corresponding nitroalkanes by an initial electron transfer process.
R. J. Kill and D. A. Widdowson, J. Chem. Soc., Chem. Commun., 1976, 755 DOI: 10.1039/C39760000755
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