Issue 14, 1973

Preparation and crystallographic characterization of a 2:1 adduct of ethynyldicarbadodecaborane(12) and trans-IrCl(CO)(PPh3)2

Abstract

Ethynyldicarbadodecaborane(12) reacted with trans-IrCl(CO)(PPh3)2 to afford the 2:1 adduct IrCl(CO)(PPh3)2(B10C4H11)(B10C4H13); X-ray crystallographic study showed the presence of σ-2-carboranylacetylide and σ-trans-2-carboranylvinyl substitutents.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 465b-466

Preparation and crystallographic characterization of a 2:1 adduct of ethynyldicarbadodecaborane(12) and trans-IrCl(CO)(PPh3)2

K. P. Callahan, C. E. Strouse, S. W. Layten and M. F. Hawthorne, J. Chem. Soc., Chem. Commun., 1973, 465b DOI: 10.1039/C3973000465B

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