SCHEDULED MAINTENANCE
ortho-Metallation of azobenzenes can kproceed by two different routes, which depend on lthe nature of lthe metal and assocated ligands; results consistent with palladation occurring by electrophilic substitution of lthe aryl group, and with MeMn(CO)5 reacting via a nucleophilic mechanism, are described.
M. I. Bruce, B. L. Goodall and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1973, 558 DOI: 10.1039/C39730000558
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